Samaresh Mondal, Gabriele Ponti, Tong Bao, Mark R. Morris, Frank Haberl, Nanda Rea, Sergio Campana

Previous studies suggest that the Galactic diffuse X-ray emission is composed of unresolved point sources, primarily mCVs. However, nearby mCVs have a much lower 6.7 keV line equivalent width ($\rm EW_{6.7}$) compared to the diffuse X-ray emission. Therefore, the primary contributors to the unresolved X-ray emission remain unclear. We detected a total of 859 sources in the 6.5-7 keV band using XMM-Newton observations of the inner Galactic disc, of which 72 sources show significant iron line emission at 6.7 keV. The distribution of spectral index $\Gamma$ for these 72 sources is bimodal, with peaks at $\Gamma=0.5\pm0.4$ and $1.8\pm0.3$, suggesting two populations of sources. The soft X-ray sources have significantly larger $\rm EW_{6.7}$ than the hard X-ray sources. Furthermore, 18 of the 32 hard sources are associated with previously known CVs. We identify CV candidates in our sample as those with spectral index $\Gamma<1.25$. The line ratio, 2-10 keV luminosity, and previous detection of spin period suggest that most of these hard sources are mCVs. The distribution of the $\rm EW_{6.7}$ line for the combined sample of previously identified and candidate CVs has a mean value of <$\rm EW_{6.7}$>$=415\pm39$ eV. Furthermore, we computed the stacked spectra of all sources detected in the 6.5-7 keV band for different flux groups, and we find evidence in the stacked spectra of hard sources that the $\rm EW_{6.7}$ increases with decreasing flux. The soft X-ray sources have <$\rm EW_{6.7}$>$=1.1\pm0.1$ keV. We identified 13 of the 30 soft sources associated with active stars, young stellar objects, and active binaries of RS CVn type. The <$\rm EW_{6.7}$> of our CV candidate sample is more than twice as large as the typical $\rm EW_{6.7}$ found in mCVs within 500 pc, and the <$\rm EW_{6.7}$> of our CV candidate sample is close to the $\rm EW_{6.7}$ value of Galactic diffuse X-ray emission.